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Van Der Waals Equation Calculator

💨 Gas Laws & Fluids. Use the Van der Waals equation formula to find pressure, volume, amount, temperature, a, b: pick the value you want, type the others, and the answer updates as you go.

(P+an2V2)(V−nb)=nRT\left(P + \dfrac{an^2}{V^2}\right)(V - nb) = nRT

Default a, b: CO₂.

Pressure0.99482 atm

Pick the ○ next to the value you want to find, fill in the others, and it solves as you type.

What each letter means

QuantityUnit
Pressureatm
VolumeL
Amountmol
TemperatureK
aL²·atm/mol²
bL/mol

Worked example

Find the pressure when Volume = 22.4 L, Amount = 1 mol, Temperature = 273 K, a = 3.59 L²·atm/mol², b = 0.0427 L/mol.

Using (P + an²/V²)(V - nb) = nRT: Pressure = 0.99482 atm.

Frequently asked questions

What is the formula for Van der Waals equation?

(P + an²/V²)(V - nb) = nRT. Default a, b: CO₂.

What do the letters stand for, and what units are used?

Pressure in atm, Volume in L, Amount in mol, Temperature in K, a in L²·atm/mol², b in L/mol.

How do you calculate pressure?

Put the values into (P + an²/V²)(V - nb) = nRT. For example, with Volume = 22.4 L, Amount = 1 mol, Temperature = 273 K, a = 3.59 L²·atm/mol², b = 0.0427 L/mol, pressure = 0.99482 atm.

Can I solve for a different value?

Yes. In the calculator above, pick the circle next to any value (pressure, volume, amount, temperature, a, b) and fill in the others: it rearranges the formula for you.

All chemistry formulas in the Chemistry Formulas See it in the Chemistry Lab simulation